Which one among the following elements is polyatomic?
- (a)Phosphorus
- (b)Sulphur
- (c)Chlorine
- (d)Aluminium
Correct — B, Sulphur. Elemental sulphur exists as the S8 molecule — eight sulphur atoms joined in a puckered ring — so it is described as poly-atomic (its atomicity is 8). Among the options only sulphur carries this 'many-atom' molecule, which is why it is the polyatomic element.
- (a)Phosphorus — White phosphorus exists as the P4 molecule — four atoms — so it is specifically classed as tetra-atomic, not poly-atomic.
- (c)Chlorine — Chlorine exists as the Cl2 molecule — two atoms — so it is diatomic, not polyatomic.
- (d)Aluminium — Aluminium is a metal held in a giant metallic lattice; in chemical formulae its atomicity is taken as 1 (monatomic), so it is not a polyatomic molecular element.
Atomicity is the number of atoms present in one molecule of an element. Noble gases are monatomic; hydrogen, oxygen, nitrogen and the halogens (including Cl2) are diatomic; ozone (O3) is triatomic and white phosphorus (P4) is tetra-atomic; sulphur (S8) is the standard example of a poly-atomic element.
The trap is phosphorus: P4 does have four atoms, but the conventional table reserves 'tetra-atomic' for P4 and 'poly-atomic' for S8. So when a question asks for the polyatomic element, sulphur is the intended answer. Do not confuse a polyatomic element (S8) with a polyatomic ion (like SO4^2-).
- Atomicity = number of atoms per molecule of an element.
- Sulphur molecule = S8 (poly-atomic, atomicity 8).
- White phosphorus = P4 (tetra-atomic); chlorine = Cl2 (diatomic).
- Metals such as aluminium are taken as monatomic (atomicity 1) in formulae.

- Choosing phosphorus (P4) as 'polyatomic' — the table classes P4 specifically as tetra-atomic.
- Confusing a polyatomic element (S8) with a polyatomic ion such as sulphate.
Asked directly as the atomicity of an element, or as 'give an example of a tetra-atomic / poly-atomic element'.
No directly related past PYQ was found.
- practice — not a real PYQ
The atomicity of ozone (O3) is:
- (a)1
- (b)2
- (c)3
- (d)4
Answer(c) 3 — ozone is a triatomic molecule made of three oxygen atoms.
- practice — not a real PYQ
Which one of the following is a diatomic molecule?
- (a)Helium
- (b)Ozone
- (c)Chlorine
- (d)Phosphorus
Answer(c) Chlorine — chlorine exists as Cl2, two atoms per molecule.