As we move to higher energy levels (larger 'n' values) in the Bohr model of a hydrogen atom, the energy difference between successive levels:
- (a)Increases continuously
- (b)Decreases continuously
- (c)Remains constant
- (d)First increases, then decreases
Answer
Why
Correct — B. In Bohr's model, the energy of level n is Eₙ = −13.6⁄n² eV.
Gap n=1→2: 13.6 × (1 − 1⁄4) = 10.2 eV
Gap n=2→3: 13.6 × (1⁄4 − 1⁄9) ≈ 1.89 eV
Gap n=3→4: 13.6 × (1⁄9 − 1⁄16) ≈ 0.66 eV
Each gap is smaller than the one before: the levels crowd together as they approach E = 0 → option (b).
Why the others are wrong
- (a)Increases continuously — The opposite of what happens. The orbit radius grows with n, as n², but the energy gaps shrink: 10.2 eV, then 1.89 eV, then 0.66 eV.
- (c)Remains constant — Equal gaps would need energy to change in equal steps with n. Bohr energy goes as 1⁄n², so equal steps in n give ever-smaller steps in energy.
- (d)First increases, then decreases — There is no rise at the start. The largest gap is the very first one, n = 1 to 2 (10.2 eV), and every later gap is smaller than the one before it.
Concept
Bohr's model gives the hydrogen electron fixed orbits with energy Eₙ = −13.6⁄n² eV: −13.6 eV at n = 1, −3.4 eV at n = 2, about −1.51 eV at n = 3.
The gap between neighbours is 13.6 × (2n + 1) ⁄ [n²(n + 1)²] eV, which falls at every step.
As n → ∞ the energy reaches 0 and the electron is free, so 13.6 eV is hydrogen's ionisation energy from the ground state.
Two quantities move in opposite directions. The energy of a level rises towards zero as n grows, while the difference between successive levels shrinks. The question asks about the difference.
Key facts
- Bohr energy of hydrogen: Eₙ = −13.6⁄n² eV.
- Ground-state energy is −13.6 eV, so hydrogen's ionisation energy is 13.6 eV.
- Orbit radius grows as n²: rₙ = 0.529 n² Å.
- Successive gaps: 10.2 eV (n = 1→2), about 1.89 eV (2→3), about 0.66 eV (3→4).
Study next
Common traps
- Confusing the energy of a level, which rises towards zero with n, with the gap between levels, which shrinks.
- Carrying the n² growth of the orbit radius over to the energy gaps.
Asked as a trend, not a value: the item is solved by the 1⁄n² dependence, and the number 13.6 eV only confirms it.
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