When electricity is passed through water, what kind of chemical reaction occurs?
- (a)Decomposition
- (b)Double displacement
- (c)Combination
- (d)Displacement
Answer
Why
Correct — A. Passing electricity through water splits it:
2H₂O → 2H₂ + O₂
One compound breaks down into two simpler substances, and that is the definition of a decomposition reaction.
Because the energy driving it is electrical, it is called electrolytic decomposition, or electrolysis.
Hydrogen collects at the cathode and oxygen at the anode in a 2:1 volume ratio. The reaction is endothermic — cut the current and it stops.
Why the others are wrong
- (b)Double displacement — Double displacement exchanges ions between two compounds, as barium chloride and sodium sulphate do. Here only one compound is present.
- (c)Combination — Combination is the reverse of what happens — two or more substances joining into a single product, as hydrogen does when it burns in oxygen to form water.
- (d)Displacement — Displacement needs a more reactive element to push a less reactive one out of its compound, like iron in copper sulphate solution. No such element is added to the water.
Concept
Decomposition reactions break a single compound into two or more products, classified by the form of energy that supplies the push.
Thermal decomposition uses heat: limestone → lime + carbon dioxide.
Electrolytic decomposition uses current: water → hydrogen + oxygen.
Photolytic decomposition uses light: silver chloride → silver + chlorine.
All three absorb energy, and that shared thread is usually the real point of the question.
In the classroom version a few drops of dilute acid are added first. Pure water conducts too poorly for the electrolysis to be seen, and the acid only carries the current — it is not consumed.
Key facts
- Electrolysis of water: 2H₂O → 2H₂ + O₂, with hydrogen at the cathode and oxygen at the anode in a 2:1 volume ratio.
- Decomposition driven by heat, by electricity and by light is called thermal, electrolytic and photolytic decomposition respectively.
- Decomposition reactions absorb energy, which is why every one of them needs heat, light or current supplied.
- Combination reactions run the other way and usually release energy.
Study next
Common traps
- Calling it displacement because two gases 'come out' — nothing is displaced, the compound simply breaks apart.
- Missing that the 2:1 hydrogen-to-oxygen ratio follows from the formula of water, not from the voltage applied.
SSC states a reaction in words or as an equation and asks for its type. Electrolysis of water and the heating of limestone are the two most repeated examples.
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